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By W. Rudzinski, D. H. Everett

All actual good surfaces are heterogeneous to a better or lesser volume and this publication offers a extensive but exact survey of the current nation of fuel adsorption. insurance is finished and extends from easy ideas to desktop simulation of adsorption. Underlying suggestions are clarified and the strengths and weaknesses of many of the equipment defined are mentioned. Key good points* Adsorption isotherm equations Read more...

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H. A. Bethe, Proc. R. Soc. London A, 150, 552 (1935). 34 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. 51. 52. 53. 54. 55. 56. 57. 58. 59. 60. 61. 62. 63. 64. 65. 66. 67. A dsorption o f Gases on Heterogeneous Surfaces T. L. Hill, J. Chem. , 18, 988 (1950). G. S. Rushbrooke & H. I. Scoins, Proc. R. Soc. London A, 230, 74 (1955). L. Onsager, Phys. , 65, 117 (1944). B. Kaufman, Phys. , 76, 1232 (1949). M. Kac & J. C. Ward, Phys. , 88, 1332 (1952). R. M. Houtappel, Physica, 16, 425 (1950).

These will act as reference points against which experimental data are to be compared. Failure of these theories to provide an adequate representation of the observed behaviour will be the motivation for questioning the assumption of homogeneity of the surface, an assumption that is common to both theories in their simplest form. 2 Therm o d yn am ics o f adsorption We begin by summarising some of the basic thermodynamic relationships which will be employed in this book. Their formulation for adsorption processes is not as straightforward as for bulk phases.

2. 28. C. Domb, Adv. Physics, 9, 149 (1960). 29. R. H. Fowler & E. A. Guggenheim, Statistical Thermodynamics, Cambridge University Press, Cambridge, 1939. 30. W. L. Bragg & E. J. Williams, Proc. R. Soc. London A, 145, 699 (1934). 31. T. L. Hill, An Introduction to Statistical Thermodynamics, Addison-Wesley Pub. , London, 1960; J. Chem. , 14, 441 (1946). 32. T. L. Hill, Statistical Mechanics, McGraw-Hill, New York, Toronto, London, 1956; G. S. Rushbrooke, Introduction to Statistical Mechanics, Oxford University Press, Oxford, 1949.

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